An Asymmetric Synthesis of Alcohols Using Chiral 2-Piperidineethanols

Title
An Asymmetric Synthesis of Alcohols Using Chiral 2-Piperidineethanols
Authors
Chung, KH.
Keywords
ENANTIOSELECTIVE ADDITION, ALDEHYDES; REAGENTS
Issue Date
1999-04
Publisher
KOREAN CHEMICAL SOC
Abstract
Optically active tertiary alcohols bearing a carbonyl function
at the a-position were synthesized enantioselectively by
using chiral 1,3-oxathianes, 1,3-oxazines or 1,3-oxazolidines.
1,2,3 The tertiary alcohols were generally prepared by
the reaction of 2-acyl derivatives with organometallics.
Among the heterocycles, 2-acyl-1,3-oxathianes have been
extensively studied to examine the diastereoselection.
URI
http://dspace.inha.ac.kr/handle/10505/20368
ISSN
0253-2964
Appears in Collections:
College of Natural Science(자연과학대학) > Chemistry (화학) > Journal Papers, Reports(화학 논문, 보고서)
Files in This Item:
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